Rapid determination of plutonium in urine using flow injection on-line preconcentration and inductively coupled plasma mass spectrometry.

V. N. Epov, et al., Journal of Analytical Atomic Spectrometry, 2005, 20 : 424-430.

High A rapid technique for the determination of Pu in urine samples using flow injection (FI) on-line preconcentration, desolvation nebulization using highly sensitive APEX device and inductively coupled plasma mass spectrometry with a dynamic sell (ICP-DRC-MS) was developed. Using the DRC avoided the necessity to separate Pu from U, and thus made the technique more rapid. Effective preconcentration and matrix separation for urine samples was achieved using TRU resin as the ion exchanger. A detection limit for 242Pu of 1.9 pg L-1 was achieved for raw, undigested urine samples using a 10 ml sample volume. The reproductibility of the method was demonstrated by recovery measurements performed on urine that had been collected from several non-exposed volunteers and spiked with Pu. 205Ti and175Lu were used as an internal standard and yeild tracer, respectively. The method provides a rapid (~11 min) means of measuring Pu in urine with no off-line sample pre-treatment, at levels below the regulatory requirements for drinking water.

other data sets for Apex:

• Apex High Sensitivity ICPMS Inlet.pdf
• Apex DRC.pdf
• Apex Element.pdf
• Apex Sodium.pdf
• Apex Trace Iron.pdf
• Apex Q Seawater Analysis.pdf
• Apex Q Rinseout Analysis.pdf
• Apex Isotope Ratio.pdf

Apex - The ICP-MS/AES
High Sensitivity Inlet System